Product ID:AEROSOL 1-1-1 TRICHLOROETHANE
MSDS Date:04/01/1989
FSC:6810
NIIN:00-930-6311
MSDS Number: BHKLW

PLAZE INCORPORATED

9401 WATSON INDUSTRIAL PARK
ST LOUIS, MO 63126
US

Emergency Phone: 314-961-3564

Info Phone: 314-961-3564

Preparer: J FERRING IV

Cage: MO273

PLAZE INCORPORATED

ST LOUIS, MO 63126 US

Telephone: 314-961-3564

Cage: MO273

METHYL CHLOROFORM (1,1,1-TRICHLOROEHANE) (SARA III)

CAS: 71-55-6

RTECS: KJ2975000

Fraction By Weight: 94.57%

OSHA PEL 350 PPM/450 STEL

ACGIH TLV: 350 PPM/450STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

1,4-DIOXANE (DIETHYLENE DIOXIDE) (SARA III)

CAS: 123-91-1

RTECS: JG8225000

Fraction By Weight: 2.45%

OSHA PEL S, 100 PPM

ACGIH TLV: S, 25 PPM; 9293

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

1,2-BUTYLENE OXIDE (SARA III)

CAS: 106-88-7

RTECS: EK3675000

Fraction By Weight: 0.46%

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

NITROMETHANE

CAS: 75-52-5

RTECS: PA9800000

Fraction By Weight: 0.33%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM; 9192

CARBON DIOXIDE

CAS: 124-38-9

RTECS: FF6400000

Fraction By Weight: 2.00%

OSHA PEL 5000 PPM

ACGIH TLV: 5000PPM/30000STEL;93

LD50 LC50 Mixture:NOT SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE IRRITATION, TRANSIENT CORNEAL
DAMAGE, SKIN IRRITATION, DEFATTING, DERMATITIS. MAY BE RAPIDLY
ABSORBED BY THE LUNGS CAUSING ASPHYXIATION.
Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT
CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT
CARCINOGENS.
Effects of Overexposure:EYE IRRITATION, SKIN IRRITATION, DERMATITIS,
ASPHYXIATION
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES: WASH WITH WATER A MINIMUM OF 15 MINUTES. SEEK MEDICAL
ATTENTION. SKIN: WASH WITH SOAP AND WATER. INGESTION: DO NOT INDUCE
VOMITING. KEEP VICTIM QUIET AND CALL PHYSICIAN IMMEDIATELY.
INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING USE MOUTH TO
MOUTH RESUSCITATION.

Flash Point Method:TOC
Flash Point:NONE
Lower Limits:7.5 %
Upper Limits:15 %
Extinguishing Media:WATER FOG
Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS,
POSITIVE PRESSURE TYPE. WATER SPRAY MAY BE USED TO KEEP CONTAINERS
COOL IN EVENT OF FIRE.
Unusual Fire/Explosion Hazard:AEROSOL CONTAINERS MAY EXPLODE VIOLENTLY
WHEN EXPOSED TO TEMPERATURES ABOVE 120F OR DIRECT HEAT.

Spill Release Procedures:ABSORB WITH INERT MATERIAL. PLACE IN METAL
CONTAINERS AND REMOVE TO OUT OF DOORS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE BELOW 120F AND AWAY FROM SOURCES
OF HEAT. DO NOT PUNCTURE, INCINERATE OR COMPACT CANS.
Other Precautions:AVOID PROLONGED CONTACT WITH ALUMINUM AND ZINC.

Respiratory Protection:FOR SPILLA AND ACCIDENTS USE A POSITIVE PRESSURE
SELF CONTAINED DEVICE
Ventilation:LOCAL EXHAUST TO KEEP CONCENTRATIONS BELOW TLV
Protective Gloves:NITRILE
Eye Protection:CHEMICAL SPLASH GOGGLES
Other Protective Equipment:AS NECESSARY TO PREVENT EXTENDED CONTACT
WITH LIQUID
Work Hygienic Practices:WASH WITH SOAP AND WATER AFTER HANDLING PRODUCT
AND BEFORE EATING DRINKING OR SMOKING.
Supplemental Safety and Health
DO NOT ALLOW TO REACH SEWER. TOXIC TO AQUATIC LIFE. AEROSOL PROPELLANT
-- CARBON DIOXIDE.

HCC:V2
Boiling Pt:B.P. Text:165F,74C
Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN
Decomp Temp:Decomp Text:385F,196C
Vapor Pres:60-80 PSI
Vapor Density:4.55
Spec Gravity:1.32
Evaporation Rate & Reference:> 1 (BUTYL ACETATE=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR LIQUID, SHARP CHLORINE SMELL, DISPERSED IN
AEROSOL

Stability Indicator/Materials to Avoid:YES
ALKALI METALS SUCH AS ALUMINUM AND ZINC POWDERED METALS. EXPOSURE TO
WATER WILL CAUSE HYDROLYSIS PRODUCING CORROSIVES
Stability Condition to Avoid:AVOID SOURCES OF HEAT
Hazardous Decomposition Products:HYDROGEN CHLORIDE AND MINUTEAMOUNTS OF
PHOSGENE AND CHLORINE.

Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING
ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSAL CONTAINER OR
LINER IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.